1993    Ph.D.,   Institute for Organic Chemistry,
                            Westfälische Wilhelms-Universität Münster, Germany
1989    M.S.,    Westfälische Wilhelms-Universität Münster, Germany
1987    B.S.,     Westfälische Wilhelms-Universität Münster, Germany

• NMR spectroscopy of quadrupolar nuclei (¹⁷O, ¹⁴N)
• Conformational and configurational studies
• Study of hydrogen bonding in organic molecules
• Development and improvement of NMR techniques

• I. Yazgan, F. J. Osonga, R. M. Miller, V. M. Kariuki, J. Zhang, J. Feng, Z. Skeete, H. Crapo, J. Schulte, and O. A. Sadik, ACS Agricultural Science & Technology 2021, 379-389 (2021),
  "Greener One-Pot Synthesis of Gold Nanoparticle Glycoconjugates Using Functionalized Sugars."
  doi:10.1021/acsagscitech.1c00093


• S. Grieco, B. Ramarao, J. Schulte, D. Kiemle, Environmental Technology & Innovation 8, 172-181 (2017),
  "Adsorption equilibrium and mechanisms of tris(2-chloroethyl)phosphate (TCEP) on zeolite-beta under environmentally relevant and competitive conditions with methyl tert-butyl ether (MTBE)."
  doi:10.1016/j.eti.2017.03.006


• F. Osonga, J. Onyango, S. Mwilu, N. Noah, J. Schulte, M. An, O. Sadik, Tetrahedron Letters 58, 1474-1479 (2017),
  "Synthesis and characterization of novel flavonoid derivatives via sequential phosphorylation of Quercetin."
  doi:10.1016/j.tetlet.2017.02.085


• V. Kariuki, J. Panetier, J. Schulte, O. Sadik , The Journal of Physical Chemistry C 120, 21027-21036 (2016),
  "Directional Templating Mechanisms of Anisotropic Nanoparticles Using Poly(Pyromellitic Dianhydride-p-Phenylene Diamine)."
  doi:10.1021/acs.jpcc.6b03369


• F. Osonga, V. Kariuki, I. Yazgan, A. Jimenez, D. Luther, J. Schulte, O. Sadik, Science of The Total Environment 564, 977-986 (2016),
  "Synthesis and antibacterial characterization of sustainable nanosilver using naturally-derived macromolecules."
  doi:10.1016/j.scitotenv.2015.12.064


• W. Qiang, W. Yau, J. Schulte, Biochemica et Biophysica Acta - Biomembranes 1848, 266-276 (2014),
  "Fibrillation of beta-amyloid peptides in the presence of phospholipid bilayers and the consequent membrane disruption."
  doi:10.1016/j.bbamem.2014.04.011


• R. Meier, R, C. Platas-Iglesias, F. W. Heinemann, G. Linti, J. Schulte, S.K. Srivastava, Inorganic Chemistry 53, 6684-6697 (2014),
  "Secrets of Solid State and Aqueous Solution Structures of [Ni(tmdta)]^2-."
  doi:10.1021/ic5004325


• J. DeCoste, D. Doetschman, M. Lahr, C. Kanyi, J. Schulte, Microporous and Mesoporous Materials 139, 110-119 (2011),
  "The Room Temperature Chemistry of Isocyanates with Zeolite NaX."
  doi:10.1016/j.micromeso.2010.10.027


• Q. Meng, D. Doetschman, A. Rizos, M. Lee, J. Schulte, A. Spyros, C. Kanyi, Environmental Science and Technology 45, 3000-3005 (2011),
  "Adsorption of Organophosphates into Microporous and Mesoporous NaX Zeolites and Subsequent Chemistry."
  doi:10.1021/es1030678


• J. DeCoste, D. Doetschman, J. Schulte, Q. Meng, Microporous and Mesoporous Materials 143, 141-148 (2011),
  "The Room Temperature Chemistry of Organo-sulfur Esters with NaX Zeolite."
  doi:10.1016/j.micromeso.2011.02.015


• C. C. Kowenje, D. Doetschman, J. Schulte, C. Kanyi, J. DeCoste, S. Yang, B. Jones, South African Journal of Chemistry 63, 6-11 (2010),
  "Effects of Copper Exchange Levels on Complexation of Ammonia in Cu(II)-exchanged X Zeolite."
  reference.sabinet.co.za/document/EJC24527


• C. Kanyi, D. Doetschman, J. Schulte, Microporous and Mesoporous Materials 124, 232-235 (2009),
  "Nucleophilic chemistry of X-type Faujasite zeolites with 2-chloroethyl ethyl sulfide (CEES), a simulant of common mustard gas."
  doi:10.1016/j.micromeso.2009.05.012


• C. Kanyi, D. Doetschman, S. Yang, J. Schulte, Microporous and Mesoporous Materials 119, 23-29 (2009),
  "The nucleophilic chemical reactions of NaX Faujasite zeolite with diisopropyl phosphorofluoridate (diisopropyl fluorophosphate, DFP."
  doi:10.1016/j.micromeso.2008.09.039


• C. Kanyi, D. Doetschman, J. Schulte, Microporous and Mesoporous Materials 117, 48-54 (2009),
  "The chemistry of alkyl dihalides in zeolite NaX at room temperature."
  doi:10.1016/j.micromeso.2008.06.005


• J. Sambur, D. Doetschman, S. Yang, J. Schulte, B. Jones, J. DeCoste, Microporous and Mesoporous Materials 112, 116-124 (2008),
  "Multiple effects of the presence of water on the nucleophilic substitution reactions of NaX Faujasite zeolite with dimethyl methylphosphonate (DMMP)."
  doi:10.1016/j.micromeso.2007.09.018


• C. Kanyi, D. Doetschman, S. Yang, J. Schulte, B. Jones, Microporous and Mesoporous Materials 108, 103-111 (2008),
  "Room temperature reactions of alkyl halides in zeolite NaX: Dehalogenation versus dehydrohalogenation."
  doi:10.1016/j.micromeso.2007.03.032


• C. Kanyi, D. Doetschman, J. Schulte, K. Yan, R. Wilson, B. Jones, C. Kowenje and S. Yang, Microporous and Mesoporous Materials 92, 292-299 (2006),
  "Linear, primary monohaloalkane chemistry in NaX and NaY faujasite zeolites with and without Na0-treatment: Zeolites as nucleophilic reagents II."
  doi:10.1016/j.micromeso.2006.01.017


• S. Yang, D. Doetschman, J. Schulte, J. Sambur, C. Kanyi, J. Fox, C. Kowenje, B. Jones and N. Sherma, Microporous and Mesoporous Materials 92, 56-60 (2006),
  "Sodium X-type faujasite zeolite decomposition of dimethyl methylphosphonate (DMMP) to methylphosphonate: Nucleophilic zeolite reactions I."
  doi:10.1016/j.micromeso.2005.12.018


• J. Schulte, J. Lauterwein, M. Klessinger, and J. Thiem, Magnetic Resonance in Chemistry 41, 123-130 (2003),
  "Configurational Assignment in Alkyl-Branched Sugars via the Geminal C,H Coupling Constants."
  doi:10.1002/mrc.1141


• J. Schulte, J. Lauterwein and U. Hoeweler, Magnetic Resonance in Chemistry 38, 751-756 (2000),
  "NMR Analysis of the Configuration and Conformation of N-Acetylneuraminosyl-(2-->3)-lactose."
  doi:10.1002/1097-458X(200009)38:9<751::AID-MRC717>3.0.CO;2-D


• M. Gallagher, P. Dougherty, P. S. Tanner, D. C. Barbini, J. Schulte, and W. E. Jones, Jr., Inorganic Chemistry 38, 2953-2956 (1999),
  "Synthesis and Characterization of Tetrahydrofurfurylcyclo-pentadienyl Molybdenum Tricarbonyl Dimer: Evidence for 19-Electron Intramolecular "Solvento" Interactions."
  doi:10.1021/ic9811603


• J. Schulte, Journal of Magnetic Resonance 134, 168-170 (1998),
  "Sequential Inversion Recovery with RIDE - Simultaneous Suppression of Two Solvent Signals in ¹⁷O NMR Spectroscopy."
  doi:10.1006/jmre.1998.1519


• J. Schulte and J. Lauterwein, Magnetic Resonance in Chemistry 34, 703-707 (1996),
  "2D ¹⁷O,¹H Chemical Shift Correlation Spectroscopy."
  doi:10.1002/(SICI)1097-458X(199609)34:9<703::AID-OMR942>3.0.CO;2-Q


• J. Schulte and J. Lauterwein, Magnetic Resonance in Chemistry 34, 527-531 (1996),
  "Application of ¹⁷O Chemical Shift Substitution Parameters to D-Hexopyranoses."
  10.1002/(SICI)1097-458X(199607)34:7<527::AID-OMR915>3.0.CO;2-K


• J. Schulte and J. Lauterwein, Journal of Magnetic Resonance - Ser. A 101, 95-97 (1993),
  "Water Suppression in ¹⁷O NMR Spectroscopy."
  doi:10.1006/jmra.1993.1014


• J. Schulte and J. Lauterwein, Magnetic Resonance in Chemistry 30, 334-337 (1992),
  "Lanthanide-Induced Shifts in the ¹⁷O NMR Spectra of 1,6-Anhydro-alpha-D-hexopyranoses. Evidence for Tridentate Complexing."
  doi:10.1002/mrc.1260300411


• J. Lauterwein, J. Schulte, M. Schumacher and M. Cerny, Magnetic Resonance in Chemistry 30, 312-319 (1992),
  "¹⁷O NMR Spectra of the 1,6-Anhydro-alpha-D-Hexopyranoses and Related Compounds. Determination of Configurational Effects on the Chemical Shifts."
  doi:10.1002/mrc.1260300408



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NMR Facilities

BU NMR Newsletter                 NMR Humor

Quick Links: Instruments Reservation NMR Courses NMR Links Chemistry Department Binghamton University






The NMR Facilitiy of the Chemistry Department is equipped with three NMR systems. Our 400 and 600 MHz instruments are located in our research building Smart Energy 0200. A 60 MHz Benchtop NMR serves the department's Instructional Program in Science II. An additional 400 MHz NMR is hosted by the Pharmacy School at the Center of Excellence. These instruments are used independently by various research students and faculty in the Chemistry, Biochemistry, Pharmacy, and Materials Science programs. Additionally, we provide NMR service and analysis to other departments on campus, as well as to various universities, colleges, and companies in the region.

Virtual NMR Lab Tour: Video (210 MB) and HTML Tours of our facility and demonstrations of our instruments can be arranged for schools, teachers, students, and researchers. To schedule tours, training, service requests, or for general NMR assistance please contact the NMR Specialist, Dr. Jürgen Schulte, Phone: (607)777-4405.

Approved rates for NMR service: $10.10 / hour - BU internal - without assistance by the NMR Specialist $24.56 / hour - BU internal - with assistance by the NMR Specialist $75.00 / hour - Service for external academia and industry users





- - - Online Schedule and Reservation of our Research Instruments - - - (NMR - - - GC/MS - - - LC/MS - - - Fluorometry)







         Our NMR Instruments:       (Click on any picture for a larger view.)
 

Chemistry Department
Bruker Avance III 600 14.1 Tesla shielded, superconducting Magnet 600 MHz Proton NMR, 3 RF Channels, z-Axis Pulsed Field Gradients  5 mm Broadband/Fluorine Observe Probe This probe is used in automation and manual operation for routine analysis of organic and inorganic compounds in solution. It is equipped for pulsed field gradients and can be tuned automatically to detect almost all nuclei. Typical experiments performed with this probe include all two-dimensional experiments, i.e. COSY, NOESY, HSQC, HMBC, and many more. 5 mm H,C,N,P Quadruple Inverse Probe This probe is used for biological and biochemical samples in solution. It is equipped for pulsed field gradients and its proton sensitivity is approx. 50% better than the BBFO probe. Multinuclear correlation experiments using almost any combination of Hydrogen, Carbon, Nitrogen, and Phosphorus are possible. Excellent water suppression capabilities make this the ideal probe for the analysis of proteins and nucleic acids in aqueous buffer solutions. 2.5 mm H,X,Y Triple Resonance MAS Probe This probe is used for the analysis of organic and inorganic compounds in solid state. The probe can spin samples at up to 35,000 Hz and it can detect almost all nuclei. Typical experiments performed with this probe include single-pulse, CP/MAS, and REDOR experiments.
Bruker Avance Neo 400 9.4 Tesla shielded, superconducting Magnet 400 MHz Proton NMR, 3 RF Channels, z-Axis Pulsed Field Gradients  5 mm BB+19F Observe "iProbe" This probe is used in automation and manual operation for routine analysis of organic and inorganic compounds in solution. It is equipped for pulsed field gradients and can be tuned automatically to detect almost all nuclei. Typical experiments performed with this probe include all two-dimensional experiments, i.e. COSY, NOESY, HSQC, HMBC, and many more. 3.2 mm H,C,N Triple Resonance CP/MAS Probe This probe is used for the analysis of organic and biochemical compounds in solid state. The probe can spin samples at up to 24,000 Hz. Typical experiments performed with this probe include single-pulse, CP/MAS, and REDOR experiments.
Pharmacy School
Bruker Avance III HD 400 9.1 Tesla shielded, superconducting Magnet 400 MHz Proton NMR, 2 RF Channels, z-Axis Pulsed Field Gradients  24-sample SampleCase Automation 5 mm Broadband/Fluorine Observe Probe This probe is typically used with an automatic sample changer for routine analysis of organic and inorganic compounds in solution. It is equipped for pulsed field gradients and can be tuned automatically to detect almost all nuclei. Typical experiments performed with this probe include all two-dimensional experiments, i.e. COSY, NOESY, HSQC, HMBC, and many more.





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Courses using NMR Spectroscopy: (may not be offered every semester)
 

CHEM 335     Demo Tour of our high-field NMR Laboratory     NMR Primer     60 MHz Benchtop NMR         CHEM 335x     Organic Synthesis with NMR Characterization of Products CHEM 411     Solid State Techniques (Solid State NMR)     Introduction to NMR with focus on Solid State NMR CHEM 422     Special Projects (1H and/or 13C NMR) CHEM 445     Quantitative 1H NMR of Xylene Isomer Mixtures     Quantitative 1H NMR of Polyethylene Glycol     300 MHz NMR Instruction sheet CHEM 455     Operating high field NMR Spectrometers        (1H pulse angle determination /     T1 measurement /     T2 measurement /     NOE + NOESY) CHEM 485f / 585f (Spring Semester)     Experimental NMR Spectroscopy in Liquids and Solids     Syllabus with Laboratory Instructions

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NMR Links:                
 

NMR Operation Manuals for our Spectrometers: Bruker Topspin Operator Manual (400 MHz with Sample Changer) Bruker Topspin Operator Manual (600 MHz without Sample changer) Tecmag NTNMR Operator Manual (300 MHz) Bruker DISNMR Operator Manual (360 & 100 MHz) NMR Processing Software for our Spectrometers: Free: Bruker Topspin Free: Tecmag NTNMR (only for our 300 MHz data) $$$: ACD-NMR with Instructions $$$: Mestrelab Mnova $$$: Felix NMR $$$: Nuts NMR NMR Companies: NMR Systems and Service: Bruker - Jeol Upgrades, Accessories, Service: Tecmag - MR Resources - Doty NMR Conferences: Experimental NMR Conference (ENC) European Magnetic Resonance Meeting (EUROMAR) International Society of Magnetic Resonance NMR Meeting (ISMAR) Small Molecule NMR Meeting (SMASH) International Conference on Magnetic Resonance in Biological Systems (ICMRBS) Online NMR Lectures: Introductory NMR and MRI Videos Introduction to NMR Spectroscopy Introduction to NMR Spectroscopy Other NMR Links: SDBS - NMR, IR, Raman, and Mass Spectroscopy Data Base SpectroscopyNow - Online Resource Serving the Spectroscopy Community NMR Periodic Table IUPAC NMR Nomenclature, Nuclear Spin Properties & Chemical Shift Conventions 1H & 13C Chemical Shifts of Common Impurities in Various Solvents




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